TANSO
炭素
W I K I

Atomic Number: 6

Group: 14

Period: 2

Block: p

Electron Config:

[He] 2s² 2p²

Atomic Mass: 12.011

Density: 2.267 g/cm³

Melting Point: 3823 K

Boiling Point: 4098 K

Electronegativity: 2.55

Covalent Radius: 77 pm

ALLOTROPES

01

sp² hybridization → planar hexagonal lattice

sp³ hybridization → tetrahedral geometry

Bond angle: 120° (graphite)

Bond angle: 109.5° (diamond)

Carbon exists in several allotropic forms — each a radically different arrangement of the same atoms. Diamond, the hardest natural material, locks carbon into a rigid tetrahedral lattice where every atom bonds to four neighbors. Graphite, soft enough to mark paper, stacks carbon into hexagonal sheets held together by weak van der Waals forces. The same element, the same electrons, the same nucleus — utterly different materials.

Fullerenes emerged in 1985 — hollow carbon cages shaped like soccer balls (C₆₀) or elongated tubes. Buckminsterfullerene, named after the geodesic dome architect, demonstrated that carbon's bonding versatility extends to closed three-dimensional structures. Carbon nanotubes, essentially rolled graphene sheets, exhibit tensile strength exceeding steel by orders of magnitude.

"Carbon is the element of infinite forms."

Graphene — a single atomic layer of graphite — was isolated in 2004 by peeling layers with adhesive tape. This two-dimensional material conducts electricity better than copper, is stronger than steel, and is nearly transparent. Amorphous carbon, lacking long-range order, appears as soot, charcoal, and activated carbon — disordered but functionally indispensable.

C₆₀ diameter: ~7.1 Å

Graphene thickness: 0.335 nm

Diamond hardness: 10 (Mohs)

Ref: Kroto et al., Nature 318, 1985

COMBUSTION

02

C + O₂ → CO₂

ΔH = −393.5 kJ/mol

Autoignition: 700°C (coal)

Flash point varies by form

Combustion is carbon's most dramatic chemical performance — the rapid exothermic oxidation that has powered human civilization since the first controlled fire 400,000 years ago. When carbon meets oxygen at sufficient temperature, the result is carbon dioxide, water vapor, and energy. The precise temperature, rate, and completeness of this reaction define the difference between a candle flame and a blast furnace.

Incomplete combustion — insufficient oxygen — produces carbon monoxide (CO), a colorless, odorless molecule that binds hemoglobin 200 times more readily than oxygen. Soot, the visible product of incomplete combustion, is amorphous carbon particulate matter suspended in exhaust gases. Every combustion engine, every furnace, every wildfire operates on the boundary between complete and incomplete oxidation.

"393.5 kJ/mol — the energy of civilization."

The chemistry of flame color reveals combustion temperature: blue flames (complete combustion, >1400°C) indicate efficient carbon-to-CO₂ conversion; yellow-orange flames indicate incandescent soot particles radiating thermal energy before full oxidation. The sunset palette of this site is the palette of carbon combustion — every warm color on screen corresponds to a temperature in a flame.

CO toxicity: 35 ppm (8hr TWA)

Flame temp (methane): 1950°C

Soot particle: 10-80 nm

CO₂ (2024) 423.0 ppm
Diamond density 3.515 g/cm³
C-12 abundance 98.93%
C-14 half-life 5,730 years
Graphite layers 0.335 nm spacing
Coal reserves 1.07 trillion tonnes
CNT tensile 63 GPa
Fullerene C₆₀ 720.64 g/mol
Charcoal porosity ~75%
Carbon fiber 3.5 GPa strength

CARBON CYCLE

03

Atmosphere: 870 GtC

Ocean: 38,000 GtC

Terrestrial: 2,000 GtC

Fossil: 10,000 GtC

The carbon cycle is the planet's longest-running chemical conversation — a continuous exchange of carbon atoms between atmosphere, ocean, lithosphere, and biosphere that has been running for 4.5 billion years. Photosynthesis pulls CO₂ from air and fixes it into organic molecules. Respiration, decomposition, and combustion return it. The cycle balances — or balanced, until industrial combustion began returning fossilized carbon to the atmosphere at geological timescales compressed into decades.

Ocean absorption accounts for roughly 30% of anthropogenic CO₂ emissions, driving ocean acidification as dissolved CO₂ forms carbonic acid. The pH of surface oceans has dropped 0.1 units since pre-industrial times — a 26% increase in hydrogen ion concentration. Coral reefs, shellfish, and calcifying plankton face dissolution of their calcium carbonate structures.

Deep geological carbon — limestone, fossil fuels, kerogen in shale — represents carbon removed from the active cycle over millions of years. Human extraction and combustion of these reserves constitutes a one-way transfer from the slow geological cycle to the fast atmospheric cycle. The rate of this transfer — approximately 10 GtC per year — has no precedent in the geological record.

pH drop: 8.2 → 8.1

Keeling Curve: Mauna Loa

Pre-industrial: 280 ppm

Annual flux: ~10 GtC/yr

ORGANIC CHEMISTRY

04

C-C bond: 154 pm

C=C bond: 134 pm

C≡C bond: 120 pm

Known compounds: >10 million

Carbon's ability to form four stable covalent bonds — and to bond with itself in chains, rings, and branched networks of arbitrary complexity — makes it the backbone of organic chemistry. No other element approaches carbon's combinatorial versatility. Silicon, often proposed as an alternative basis for life, forms weaker bonds, cannot sustain long chains, and produces insoluble oxides rather than the gaseous CO₂ that enables the carbon cycle.

Hydrocarbons — molecules of only carbon and hydrogen — range from methane (CH₄, one carbon) to polyethylene (chains of thousands). Adding oxygen produces alcohols, aldehydes, ketones, carboxylic acids. Adding nitrogen yields amines, amides, nitriles. The permutations are effectively infinite — over 10 million organic compounds have been catalogued, with new ones synthesized daily.

"10,000,000+ compounds and counting."

Biochemistry is organic chemistry in water — proteins fold from amino acid chains, DNA encodes information in nucleotide sequences, lipids self-assemble into membranes, and carbohydrates store solar energy as chemical bonds. Every living organism is a carbon-based machine running carbon-based software. Life, as we know it, is carbon's most elaborate allotrope.

DNA bases: A, T, G, C

Amino acids: 20 standard

Protein: C, H, O, N, S

ISOTOPES

05

C-12: 6p + 6n (stable)

C-13: 6p + 7n (stable)

C-14: 6p + 8n (β⁻ decay)

Carbon has 15 known isotopes, but three dominate terrestrial chemistry. Carbon-12, with six protons and six neutrons, constitutes 98.93% of natural carbon and serves as the definition of the atomic mass unit. Carbon-13 (1.07%) is stable but heavier — its presence in organic molecules provides the basis for ¹³C NMR spectroscopy, one of chemistry's most powerful structural tools.

Carbon-14 is radioactive — formed continuously in the upper atmosphere when cosmic-ray neutrons strike nitrogen-14 atoms. With a half-life of 5,730 years, C-14 incorporates into living organisms through photosynthesis and the food chain. Upon death, C-14 intake ceases and the isotope decays predictably. This clock — radiocarbon dating — has revolutionized archaeology, paleontology, and climate science, providing absolute dates for organic materials up to ~50,000 years old.

"5,730 years — the half-life of memory."

¹³C NMR: δ 0-220 ppm

C-14 dating limit: ~50 ka

Libby, 1949 (Nobel 1960)

Graphene conductivity ~10⁸ S/m
Diamond refractive 2.417
Earth carbon 0.02% by mass
Solar abundance 4th most common
Triple point 4,600 K, 10.8 MPa
Bond energy C-C 346 kJ/mol

INDUSTRIAL CARBON

06

Steel: 0.2-2.1% carbon

Activated carbon: 3000 m²/g

Carbon black: $17B market

Carbon is the defining ingredient of steel — iron's mechanical properties transform with carbon content from soft wrought iron (<0.08% C) through medium-carbon structural steel (0.3-0.6% C) to hard tool steel (0.6-1.5% C) and brittle cast iron (2-4% C). The entire industrial revolution was, in essence, an exercise in controlling carbon content in iron.

Activated carbon — amorphous carbon processed to maximize surface area — adsorbs impurities from water, air, and industrial processes. A single gram can have a surface area exceeding 3,000 square meters. Carbon fiber, produced by carbonizing polymer precursors at temperatures above 1000°C, combines extreme tensile strength with low weight — enabling aerospace structures, racing vehicles, and wind turbine blades.

Carbon black — fine particles produced by incomplete combustion of hydrocarbons — reinforces rubber in every tire on every road. Carbon electrodes enable aluminum smelting, electric arc furnaces, and battery technology. From pencils (graphite) to cutting tools (diamond) to semiconductors (silicon carbide), carbon's industrial applications span virtually every sector of material production.

Carbon fiber: 1.75 g/cm³

SiC hardness: 9-9.5 Mohs

Graphite lubricant: dry conditions